Cobalt complexes with the 1-[2-(N,N-dimethylamino)ethyl]-2,3,4,5-tetramethylcyclopentadienyl ligand
نویسندگان
چکیده
منابع مشابه
Rhodium and Iridium Complexes with the 1 - ( 2 - ( Dimethylamino ) ethyl ) - 2 , 3 , 4 , 5 - tetramethylcyclopentadienyl Ligand
published in Advance ACS Abstracts, August 1, 1994. (1) Jutzi, P.; Heidemann, T.; Neumann, B.; Stammler, H.-G. J. (2) Avey, A.; Weakley, T. J . R.; Tyler, R. J. Am. Chem. Soc. 1993, (3) Jutzi, P.; Dahlhaus, J. Synthesis 1993, 684-686. (4) (a) Jutzi, P.; Dahlhaus, J.; Kristen, M. 0. J. Organomet. Chem. 1993, 450, Cl-C3. (b) Jutzi, P.; Dahlhaus, J.; Bangel, M. J. Organomet. Chem. 1993,460, C13-Cl...
متن کاملTris(2-dimethylaminoethyl)amine: a simple new tripodal polyamine ligand for Group 1 metals.
The first examples of Group 1 metal complexes of tris(2-dimethylaminoethyl)amine (Me(6)TREN) are reported including monomeric sodium complexes containing eta(4)-bound ligands, suggesting their potential use in alkali-metal-mediated synthetic applications.
متن کاملSynthesis and Characterization of Metal Complexes with New Unsymmetrical Schiff Base Ligand Derived from 2-Aminoethanethiol
A new unsymmetric thioether diamine N - ( 2 - ( 2 - aminophenylthio) ethyl) benzene - 1 , 2 - diamine was prepared through the nucleophilic substitution of cysteaminium chloride with 1 - chloro - 2 - nitrobenzene and then the nitro groups of prepared compuond converted to the amine by zinc powder and ammonium chloride. Then, unsymmetric Schiff bass ligand 2 - ((( 2 - (( 2 - (( 2 - (( 2 - hydrox...
متن کاملSynthesis and reactivity of cobalt complexes derived from tris(2-pyridylthio)methane ligand: Structural characterization of cobalt(III) complexes containing cobalt–carbon bond
The synthesis, characterization and reactivity of a cobalt(II) complex, [(HL)Co(PyS)](ClO4) (1) (where HL = tris(2-pyridylthio)methane and PyS = monoanionic pyridine-2-thiolate) are discussed. Complex (1) reacts with molecular oxygen to yield a mononuclear low-spin cobalt(III) complex, [(L)Co(PyS)](ClO4) (2). On the other hand, treatment of (1) with a protic acid (pyridinium perchlorate) follow...
متن کاملSynthesis, Spectroscopy and Magnetic Characterization of Five Dinuclear Copper(II) Complexes with 2, 3 or 4-Pyridinemethanol as the Ligand
The synthesis, spectroscopy and magnetic characterization of five new dinuclear copper(II) complexes are described. All five compounds have the general formula [Cu2(L)4(O-R)2](Cl)2 or [Cu2(L)2(Cl)2](Cl)2, in which R = CH3 or H, L=2, 3 or 4-pyridinemethanol as L2, L3 or L4, respectively. The title compounds consist of dinuclear units with bridging methoxo groups in [Cu2(L4)4(O-CH3)2](Cl)2, hydro...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Organometallics
سال: 1993
ISSN: 0276-7333,1520-6041
DOI: 10.1021/om00032a020